You should be able to use some epoxy in the area that is leaking into the PV area, dont throw away the cylinder or give up.
you just need to clean it real well and use a good epoxy like Devcon, it takes just need a small amount to to fix this.
I mentioned this before adding cooling around the exhaust port is not going to fix a overheating problem but it will allow the exhaust side of the piston run cooler and be less prone to seizing.
You are only going to fix a overheating problem by removing more heat at the radiator
^^^ This is good advice. Too many people forget that as you increase the size of your engine to these big bores, the heat rejection requirements for the engine go up as well. A factory 250R radiator will only do so much. You have 2 options to increase the heat rejection capacity of your cooling system: 1. increase the size of the radiator 2. increase the air flow through your radiator.
The 2nd option is basically fixed unless you mount a fan to the radiator or go with a shroud design that actually forces air through the fins when the quad is moving (most of the shroud designs don't)
The only other option left is to increase the size of the radiator. One other additional option that could help would be to run an oversize rad that has a dual pass setup, like AFCO. I think there is another brand that may also offer this.
It sounds like you may have messed up the cylinder out of haste. If so, it happens, but don't give up. Just take a breath. It can be easily fixed. Hang it there.